DITHIADIAZAFULVALENES - NEW STRONG ELECTRON-DONORS - SYNTHESIS, ISOLATION, PROPERTIES, AND EPR STUDIES

被引：52

作者：

TORMOS, GV ^{[1
]}

BAKKER, MG ^{[1
]}

WANG, P ^{[1
]}

LAKSHMIKANTHAM, MV ^{[1
]}

CAVA, MP ^{[1
]}

METZGER, RM ^{[1
]}

机构：

[1] UNIV ALABAMA,DEPT CHEM,TUSCALOOSA,AL 35487

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1995年 / 117卷 / 33期

关键词：

D O I：

10.1021/ja00138a006

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Several dithiadiazafulvalenes, which are potent electron donors, were isolated as pure compounds for the first time. Solid charge-transfer complexes with TCNQ and also cation-radical and dication salts with perchlorate gegenions were obtained. Two of the TCNQ complexes are moderately conductive at room temperature (0.083 and 0.011 S/cm). A solution EPR study, combined with theoretical calculations, allowed the determination of the relative equilibrium cation-radical and anion-radical concentrations.

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页码：8528 / 8535

页数：8

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