GAS-PHASE ACTIVATION OF FLUOROCARBONS BY BARE AND COORDINATED PRASEODYMIUM CATIONS

被引：40

作者：

HEINEMANN, C

GOLDBERG, N

TORNIEPORTHOETTING, IC

KLAPOTKE, TM

SCHWARZ, H

机构：

[1] TECH UNIV BERLIN,INST ORGAN CHEM,D-10623 BERLIN,GERMANY

[2] TECH UNIV BERLIN,INST ANORGAN & ANALYT CHEM,W-1000 BERLIN,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 02期

关键词：

FLUOROCARBONS; LANTHANIDE COMPOUNDS; MASS SPECTROMETRY;

D O I：

10.1002/anie.199502131

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Rather than CH or CC bonds, Pr+ activates CF bonds in the gas phase in a variety of aliphatic and aromatic fluorocarbons; PrF+ and PrO+ react analogously. This first general example of preferential CF bond activation in the gas phase allows interesting conclusions to be drawn regarding the importance of 4f electrons for the reactivity of isolated lanthanide species. The existence of neutral PrF and PrF2 in the gas phase was also proven by neutralization–reionization mass spectrometry (NRMS). Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：213 / 217

页数：5

共 49 条

[1] CATALYTIC ACTIVATION OF CARBON-FLUORINE BONDS BY A SOLUBLE TRANSITION-METAL COMPLEX
AIZENBERG, M
MILSTEIN, D
[J]. SCIENCE, 1994, 265 (5170) : 359 - 361
[2] ARMENTROUT PB, 1990, ANNU REV PHYS CHEM, V41, P313
[3] THERMOCHEMISTRY OF URANIUM HALIDE-IONS - REACTIONS OF U+ WITH CH3F, SIF4, CH3CL, AND CCL4
ARMENTROUT, PB
BEAUCHAMP, JL
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1981, 85 (26) : 4103 - 4105
[4] GENERATION, FRAGMENTATION, AND INTERCONVERSION PROCESSES OF [FE,C-6,H-6,O](+) ISOMERS RELEVANT FOR THE OXYGENATION OF AROMATIC-HYDROCARBONS
BECKER, H
SCHRODER, D
ZUMMACK, W
SCHWARZ, H
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (03) : 1096 - 1100
[5] GAS-PHASE REACTIONS OF FE+ WITH AROMATIC-COMPOUNDS - MONOSUBSTITUTED BENZENE-DERIVATIVES
BJARNASON, A
TAYLOR, JW
[J]. ORGANOMETALLICS, 1990, 9 (05) : 1493 - 1499
[6] REACTIONS OF SC+, TI+, V+, FE+, CO+ AND NI+ WITH 1-FLUORONAPHTHALENE IN THE GAS-PHASE - METAL-CATALYZED OLIGOMER FORMATION AND OBSERVATION OF UNUSUAL RING FRAGMENTATION
BJARNASON, A
[J]. RAPID COMMUNICATIONS IN MASS SPECTROMETRY, 1994, 8 (05) : 366 - 370
[7] REACTIONS OF 1ST-ROW TRANSITION-METAL IONS (SC+-ZN+) WITH PHENYL HALIDES IN THE GAS-PHASE
BJARNASON, A
[J]. ORGANOMETALLICS, 1991, 10 (05) : 1244 - 1247
[8] BJARNASON A, 1988, ORGANOMETALLICS, V8, P2020
[9] CORNEHL HH, IN PRESS ORGANOMETAL
[10] ORGANOLANTHANOIDS .4. SOME REACTIONS OF BIS(POLYFLUOROPHENYL)YTTERBIUM COMPOUNDS
DEACON, GB
MACKINNON, PI
TUONG, TD
[J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1983, 36 (01) : 43 - 53

← 1 2 3 4 5 →