SURFACE-PROPERTIES OF MAGNESIUM-OXIDE OBTAINED FROM MAGNESIUM-HYDROXIDE - INFLUENCE ON PREPARATION AND CALCINATION CONDITIONS OF MAGNESIUM-HYDROXIDE

被引：41

作者：

CHOUDHARY, VR

PANDIT, MY

机构：

来源：

APPLIED CATALYSIS | 1991年 / 71卷 / 02期

关键词：

MAGNESIUM OXIDE; SURFACE PROPERTIES; CALCINATION; BASICITY; CATALYST PREPARATION (PRECIPITATION);

D O I：

10.1016/0166-9834(91)85084-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Surface area, basicity and base strength distribution (weak, strong and intermediate strength basic sites) of magnesium oxide obtained from magnesium hydroxide prepared using different magnesium salts, precipitating agents, precipitating conditions (viz. concentration, pH and temperature) and aging periods, and calcined at different temperatures (873-1173 K) have been investigated. The basicity and base strength distribution on the different magnesium oxide samples have been determined by stepwise thermal desorption of carbon dioxide from 323 to 1173 K. The surface properties are found to be strongly influenced by the above preparation conditions of magnesium hydroxide and also by its calcination temperature.

引用

页码：265 / 274

页数：10

共 20 条

[1] ASAMI K, 1986, CHEM LETT, P1223
[2] OXIDATIVE DIMERIZATION OF METHANE OVER LEAD-MAGNESIUM MIXED OXIDE CATALYSTS
Bartek, J. P.
Hupp, J. M.
Brazdil, J. F.
Grasselli, R. K.
[J]. CATALYSIS TODAY, 1988, 3 (2-3) : 117 - 126
[3] CHARACTERIZATION AND REACTIVITY OF MONONUCLEAR OXYGEN SPECIES ON OXIDE SURFACES
CHE, M
TENCH, AJ
[J]. ADVANCES IN CATALYSIS, 1982, 31 : 77 - 133
[4] A NOVEL METHOD FOR MEASURING BASE STRENGTH DISTRIBUTION ON BASIC SOLID CATALYSTS UNDER OPERATING-CONDITIONS
CHOUDHARY, VR
RANE, VH
[J]. CATALYSIS LETTERS, 1990, 4 (01) : 101 - 106
[5] INFLUENCE OF VARIOUS PROMOTERS ON THE BASICITY AND CATALYTIC ACTIVITY OF MGO CATALYSTS IN OXIDATIVE COUPLING OF METHANE
CHOUDHARY, VR
RANE, VH
CHAUDHARI, ST
[J]. CATALYSIS LETTERS, 1990, 6 (01) : 95 - 98
[6] OXIDATIVE COUPLING OF METHANE TO C-2 HYDROCARBONS OVER LA-PROMOTED MGO CATALYSTS
CHOUDHARY, VR
CHAUDHARI, ST
RAJPUT, AM
RANE, VH
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (09) : 555 - 556
[7] CHOUDHARY VR, 1989, RES IND, V34, P258
[8] CHOUDHARY VR, 1987, RECENT TRENDS CHEM R, V1, P90
[9] CHOUDHARY VR, 1989, 1ST IND FRENCH S CAT
[10] SELECTIVE OXIDATIVE COUPLING OF METHANE OVER SUPPORTED ALKALINE-EARTH METAL HALIDE CATALYSTS
FUJIMOTO, K
HASHIMOTO, S
ASAMI, K
OMATA, K
TOMINAGA, H
[J]. APPLIED CATALYSIS, 1989, 50 (03): : 223 - 236

← 1 2 →