THE 4-ELECTRON OXIDATION OF MESO-OCTAETHYLPORPHYRINOGEN VIA A METAL-MEDIATED DEALKYLATION PROCESS - FORMATION OF [RUL(PHCN)2] [H2L = 5,15-DIHYDRO-5,5,10,15,15,20-HEXAETHYLPORPHYRIN]

被引：14

作者：

PIARULLI, U

FLORIANI, C

CHIESIVILLA, A

RIZZOLI, C

机构：

[1] UNIV LAUSANNE,INST CHIM MINERALE & ANALYT,PL CHATEAU 3,CH-1005 LAUSANNE,SWITZERLAND

[2] UNIV PARMA,CNR,CTR STUDIO STRUTT DIFFRATTOMETR,IST STRUTT CHIM,I-43100 PARMA,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 07期

关键词：

D O I：

10.1039/c39940000895

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A four-electron oxidation of meso-octaethylporphyrinogen (H4L') involving the dealkylation of two meso carbons has been observed in the reaction between [Ru(Cl)2(PhCN)4] and [Li4L'(THF)4] leading to [RuL(PhCN)2] which contains two hemiporphyrin fragments joined by two sp3 carbons, as shown by an X-ray analysis.

引用

页码：895 / 896

页数：2

共 28 条

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