NOVEL RADICAL-CATION SALTS OF ORGANIC PI-DONORS CONTAINING IODINE ATOM(S) - THE FIRST APPLICATION OF STRONG INTERMOLECULAR -I-X- (X=CN, HALOGEN ATOM) INTERACTION TO MOLECULAR CONDUCTORS

被引:114
作者
IMAKUBO, T [1 ]
SAWA, H [1 ]
KATO, R [1 ]
机构
[1] UNIV TOKYO,INST SOLID STATE PHYS,MINATO KU,TOKYO 106,JAPAN
关键词
RADICAL CATION SALTS; IODINE; TETRATHIAFULVALENE; MOLECULAR CONDUCTORS; CRYSTAL DESIGN;
D O I
10.1016/0379-6779(95)03322-X
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
As a new architecture of crystal design in molecular conductors, an application of the intermolecular -I ... X- (X = CN, halogen atom) interaction is presented. Novel radical cation salts of iodine-bonded tetrathiafulvalene (TTF) derivatives have been prepared and their unique crystal structures containing strong and directional cation-anion interactions are characterized.
引用
收藏
页码:117 / 122
页数:6
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