N2-BINDING MONONUCLEAR RUTHENIUM(II) TERTIARY POLYAMINE COMPLEX BY DIRECT ACTION OF GASEOUS NITROGEN IN AQUEOUS-SOLUTION

被引：8

作者：

TAKAHASHI, T ^{[1
]}

HIRATANI, K ^{[1
]}

KIMURA, E ^{[1
]}

机构：

[1] HIROSHIMA UNIV, SCH MED, DEPT PHARMACEUT CHEM, MINAMI KU, HIROSHIMA 734, JAPAN

来源：

CHEMISTRY LETTERS | 1993年 / 08期

关键词：

D O I：

10.1246/cl.1993.1329

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tertiary polyamine ruthenium(III) complex trans-[RuCl2(L)]+ (L = 2,5,9,12-tetramethyl-2,5,9,12-tetraazatridecane) has been prepared which can react with Mg and an atmospheric N2 gas in aqueous solution at room temperature to yield the first N2-binding ruthenium(II) tertiary polyamine complex trans-[RuCl(L)(N2)]+ that is converted into trans-[Ru(OH)(L)(N2)]+ and trans-[Ru(L)(N2)(OH2)]2+.

引用

页码：1329 / 1332

页数：4

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