Complexes of lanthanum with radical anions of 2,2-bipyridyl and 3,6-di-tert-butyl-o-benzoquinone

被引：2

作者：

Fedushkin, IL ^{[1
]}

Nevodchikov, VI ^{[1
]}

Bochkarev, MN ^{[1
]}

机构：

[1] RUSSIAN ACAD SCI,GA RAZUVAEV INST ORGANOMET CHEM,NIZHNII NOVGOROD 603600,RUSSIA

来源：

RUSSIAN CHEMICAL BULLETIN | 1995年 / 44卷 / 11期

关键词：

lanthanum; radical-anion ligands; ESR spectra;

D O I：

10.1007/BF00696729

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Complexes of a rare-earth element containing only one radical-anion ligand have been synthesized and isolated in pure states for the first time. The LaI2(bPY)(THF)(3) complex has been prepared from [LaI2(THF)(3)](2)(C10H8) and 2,2-bipyridyl in DME. The semiquinone complex LaI2(SQ)(THF)(3) has been obtained by reaction of lanthanum iodide with 3,6-di-tert-butyl-o-benzoquinone in THF in the presence of lanthanum powder. ESR spectra of the complexes have been studied.

引用

页码：2185 / 2186

页数：2