STRUCTURAL STUDY OF AMORPHOUS CO-FERRITE FILM BY ANOMALOUS X-RAY-SCATTERING

The structure of amorphous Co-ferrite film grown on a glass substrate was studied by anomalous X-ray scattering (AXS). Co atoms cannot be distinguished from Fe atoms with the usual X-ray diffraction technique. Therefore the AXS method at the Fc and Co K-absorplion edges was adopted. In the previous AXS studies only the lewer energy side of the absorption edges was adopted. In the previous AXS studies only the lower energy side of the absorption edge was used. In the present case, the lower energy side of the Co K-absorption edge corresponds to the higher energy side of the Fe K-absorption edge. Therefore, in order to overcome this inconvenience, the scattering was measured on both sides of the absorption edge, thus enabling the independent determination of the oxygen coordination numbers around Co and Fe in the ferrite film from the environmental RDFs estimated from the energy differential profiles by coupling with the linear least squares technique. © 1990, Walter de Gruyter. All rights reserved.