SELECTIVE KETONE PYROLYSIS - NEW SYNTHETIC METHOD FOR MONOCYCLIC AND POLYCYCLIC-HYDROCARBONS

被引：27

作者：

BREITENBACH, J ^{[1
]}

OTT, F ^{[1
]}

VOGTLE, F ^{[1
]}

机构：

[1] UNIV BONN,INST ORGAN CHEM,GERHARD DOMAGK STR 1,W-5300 BONN 1,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 03期

关键词：

D O I：

10.1002/anie.199203071

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ring formation with p-toluenesulfonylmethyl isocyanide (TosMIC), and successive CO loss, leads preparatively to hitherto unobtainable or not easily obtained polycyclic hydrocarbons. From the triketone 1, the ketone intermediates 2 and 3 and the hydrocarbon 4 can be isolated.

引用

页码：307 / 308

页数：2

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