SEQUENTIAL ARENE COORDINATION AND C-F INSERTION IN THE REACTIONS OF (ETA-5-PENTAMETHYLCYCLOPENTADIENYL)RHODIUM COMPLEXES WITH HEXAFLUOROBENZENE

被引：84

作者：

JONES, WD ^{[1
]}

PARTRIDGE, MG ^{[1
]}

PERUTZ, RN ^{[1
]}

机构：

[1] UNIV YORK,DEPT CHEM,YORK YO1 5DD,N YORKSHIRE,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 04期

关键词：

D O I：

10.1039/C39910000264

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hexafluorobenzene reacts with [(eta-5-C5Me5)Rh(PMe3)(C2H4)] in two sequential photochemical reactions to yield first the arene coordination product, [(eta-5-C5Me5)Rh(PMe3)(eta-2C6F6)], and then the C-F insertion product, [(eta-5-C5Me5)Rh(PMe3)(C6F5)F]; chlorination of the latter generates [(eta-5-C5Me5)Rh(PMe3)(C6F5)Cl], the structure of which has been determined crystallographically.

引用

页码：264 / 266

页数：3

共 17 条

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