STRUCTURE OF BIS(DIPICOLINATO)FERRATE(III) DIHYDRATE

被引：15

作者：

COUSSON, A ^{[1
]}

NECTOUX, F ^{[1
]}

RIZKALLA, EN ^{[1
]}

机构：

[1] AIN SHAMS UNIV,FAC SCI,CAIRO,EGYPT

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1992年 / 48卷

关键词：

D O I：

10.1107/S0108270192002877

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Fe atom is octahedrally surrounded by two tridentate dipicolinate anions. These two ligands are orthogonal to each other. The two water molecules are linked through the proton required for electricial neutrality and form an H5O2 cation. The protons of these two water molecules are bonded to the O atoms of the carboxylate groups which are not coordinated to the Fe atom. Metal-nitrogen and metal-oxygen distances are comparable to those of other transition-metal dipicolinate complexes.

引用

页码：1354 / 1357

页数：4

共 16 条

[1] ULTRAVIOLET-ABSORPTION SPECTRA OF DRY BACTERIAL SPORES [J].