DECAY CHANNELS OF CORE-EXCITED AND IONIZED HCL STUDIED BY TIME-OF-FLIGHT MASS-SPECTROSCOPY

被引：27

作者：

AKSELA, H

AKSELA, S

HOTOKKA, M

YAGISHITA, A

SHIGEMASA, E

机构：

[1] SWEDISH UNIV ABO,DEPT PHYS CHEM,SF-20500 TURKU,FINLAND

[2] NATL LAB HIGH ENERGY PHYS,PHOTON FACTORY,TSUKUBA,IBARAKI 305,JAPAN

来源：

JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS | 1992年 / 25卷 / 15期

关键词：

D O I：

10.1088/0953-4075/25/15/016

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

The decay channels of HCl after excitation of Cl 2p electrons to different resonance states below the ionization threshold have been studied by measuring the ionic fragments using time-of-flight mass spectrometry. The fragmentation at resonances is found to deviate significantly from that obtained above the ionization threshold. The fragmentation is also observed to depend strongly on whether the 2p(Cl) electron is excited to the antibonding sigma* orbital or to the Rydberg orbitals. The interpretation is based on theoretical calculations.

引用

页码：3357 / 3370

页数：14

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