ORTHO-SUBSTITUTED ARYL SULFOXIDES DESIGNED FOR HIGHLY DIASTEREOSELECTIVE RADICAL REACTIONS

被引：23

作者：

RENAUD, P

BOURQUARD, T

机构：

[1] Université de Fribourg, Institut de Chimie Organique

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 11期

关键词：

D O I：

10.1016/0040-4039(94)88325-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Radical allylation of 1-arenesulfinylethyl radicals has been examined for different ortho-substituted aryl groups. High level of diastereoselectivity (up to 95 % ds) has been achieved with the o-chlorobenzenesulfinyl group. Rationalization of the results based on ground state conformation of the radicals is presented.

引用

页码：1707 / 1710

页数：4

共 5 条

[1] GROUND-STATES OF MOLECULES .48. MINDO-3 STUDY OF SOME RADICAL-ADDITION REACTIONS [J].