EXPANSION OF THE NITRILE CAPPED CLUSTER FE3(CO)9(N-CPH)

被引：7

作者：

BANTEL, H ^{[1
]}

SUTER, P ^{[1
]}

VAHRENKAMP, H ^{[1
]}

机构：

[1] UNIV FREIBURG,INST ANORGAN & ANALYT CHEM,D-79104 FREIBURG,GERMANY

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 09期

关键词：

D O I：

10.1021/om00009a055

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of the cluster Fe-3(CO)(9)(mu(3)-eta(2)-N=CPh) (1) with the cluster expansion reagents Fe-2(CO)(9), CpRh(CO)(2), and Ru-3(CO)(12) results in. the formation of the tetranuclear clusters Fe-3(CO)(9)ML(n)(mu(4)-eta(2)-N=CPh) (2a, ML(n) = Fe(CO)(3); 2b, ML(n) = RhCp; 2c, ML(n) = Ru(CO)(3)). The butterfly shape of these clusters and the unsymmetrical capping mode of the benzonitrile ligand were confirmed by structure determination of the Fe3Ru cluster 2c.

引用

页码：4424 / 4426

页数：3

共 18 条

[1]

ADAMS RD, 1985, PROG INORG CHEM, V33, P127

[2] ALKYNE-REVERSIBLE-VINYLIDENE REARRANGEMENTS ON TETRANUCLEAR CLUSTERS [J].

ALBIEZ, T ;

POWELL, AK ;

VAHRENKAMP, H .

CHEMISCHE BERICHTE, 1990, 123 (04) :667-675

[3] ALKYNE-BRIDGED TETRANUCLEAR CLUSTERS BY EXPANSION OF TRINUCLEAR CLUSTERS [J].

BANTEL, H ;

POWELL, AK ;

VAHRENKAMP, H .

CHEMISCHE BERICHTE, 1990, 123 (04) :677-684

[4] A SYSTEMATIC ENTRY TO BUTTERFLY-TYPE [M4(CO)12(MU-4-XY) CLUSTERS [J].

BANTEL, H ;

HANSERT, B ;

POWELL, AK ;

TASI, M ;

VAHRENKAMP, H .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (08) :1059-1060

[5]

BANTEL H, 1989, ANGEW CHEM, V101, P1084

[6] ANIONIC FE3P CLUSTERS - PREPARATION AND REACTIONS INVOLVING FRAMEWORK CHANGES [J].

DECK, W ;

SCHWARZ, M ;

VAHRENKAMP, H .

CHEMISCHE BERICHTE-RECUEIL, 1987, 120 (09) :1515-1521

[7] DERIVATIVE CHEMISTRY OF THE CLUSTER RU4(CO)12(MU-4-ETA-2-N2ET2) [J].

HANSERT, B ;

VAHRENKAMP, H .

CHEMISCHE BERICHTE-RECUEIL, 1993, 126 (09) :2023-2026

[8]

HANSERT B, 1991, CHEM BER, V124, P2679

[9] BENZONITRILE AS A 6-ELECTRON DONOR LIGAND - THE CLUSTERS FE3(CO)9(MU-3(ETA-2)-NCC6H5) AND FE4(CO)12(MU-4(ETA-2)-NCC6H5) [J].

KELLER, E ;

WOLTERS, D .

CHEMISCHE BERICHTE-RECUEIL, 1984, 117 (04) :1572-1582

[10]

KELLER E, 1993, SCHAKAL

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