VICINAL C-13-C-13 COUPLING-CONSTANTS IN BICYCLIC MONOTERPENES

被引：9

作者：

DENISOV, AY

TKACHEV, AV

MAMATYUK, VI

机构：

[1] Institute of Organic Chemistry, Siberian Branch of the Ussr Academy of Sciences, Novosibirsk

来源：

MAGNETIC RESONANCE IN CHEMISTRY | 1992年 / 30卷 / 02期

关键词：

C-13; NMR; C-13-C-13 COUPLING CONSTANTS; SELECTIVE VERSION OF INADEQUATE; 3-CARENE; ALPHA-PINENE; CAMPHENE;

D O I：

10.1002/mrc.1260300202

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Carbon-carbon coupling constants in monoterpene hydrocarbons (3-carene, alpha-pinene and camphene) were investigated. A selective version of the INADEQUATE experiment was used for measurements of the long-range (n)J(CC) values. The dependence of the vicinal C-13-C-13 coupling constants on the dihedral angles and the types of molecular framework involved within the direct coupling path is discussed. The configuration of a heteroatomic derivative from alpha-pinene was determined from its 3J(CC) values.

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页码：95 / 100

页数：6

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