THE REACTION OF BETA-(TRIMETHYLSILYL)ALKYL PHENYL SULFONES WITH OXIRANES - A METHOD FOR STEREOCONTROLLED SYNTHESIS OF HOMOALLYLIC ALCOHOLS

被引：16

作者：

KABAT, MM ^{[1
]}

WICHA, J ^{[1
]}

机构：

[1] POLISH ACAD SCI,INST ORGAN CHEM,UL KASPRZAKA 44,PL-01224 WARSAW,POLAND

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 08期

关键词：

D O I：

10.1016/S0040-4039(00)74491-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of beta-trimethylsilylalkyl sulfones (4a-4b) with oxirane derivatives (5a - 5d, 9) followed by treatment of the immediate adducts with sodium hydride, affords O-trimethylsilyl homoallylic alcohols (7a - 7e, 11), mainly (Z) isomers.

引用

页码：1073 / 1076

页数：4

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