PALLADIUM-CATALYZED REACTIONS OF 2-ALKYNYL CARBONATES WITH OLEFINS - A NEW SYNTHETIC METHOD FOR VINYL ALLENES

被引：42

作者：

MANDAI, T

OGAWA, M

YAMAOKI, H

NAKATA, T

MURAYAMA, H

KAWADA, M

TSUJI, J

机构：

[1] Department of Applied Chemistry. Okayama University of Science, Okayama, 700, Ridai-cho

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 28期

关键词：

PROPARGYLIC CARBONATES; 1,2,4-TRIENES; ALLENYLPALLADIUM COMPLEX;

D O I：

10.1016/S0040-4039(00)92717-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Palladium-catalyzed reaction of 2-alkynyl carbonates (propargylic carbonates) with olefins proceeds smoothly in the presence of triethylamine and potassium bromide to give vinyl allenes (1,2,4-trienes) in good yields.

引用

页码：3397 / 3398

页数：2

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