TRAPPING SITES OF HYDROGEN-ATOMS IN SOLID HYDROGEN AT 4.2-K ANALYZED BY ESR LINEWIDTHS

被引：22

作者：

MIYAZAKI, T

MORIKITA, H

FUEKI, K

HIRAKU, T

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Nagoya University, Chikusa-ku, Nagoya, 464-01, Furo-cho

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 182卷 / 01期

关键词：

D O I：

10.1016/0009-2614(91)80099-J

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

ESR spectra of H (D) atoms, produced in gamma-irradiated solid hydrogen were studied at 4.2 K. The ESR linewidth of the trapped hydrogen atoms depends significantly upon the matrices of hydrogen isotopes. The ESR linewidth has been calculated with the orthogonalized wavefunction on the basis of the model presented. It is concluded from the comparison of the experimental ESR linewidths with theoretical ones that H atoms in solid H-2 are trapped in substitutional sites, while H (D) atoms in solid HD and D2 are trapped in interstitial octahedral sites.

引用

页码：35 / 38

页数：4

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