INSTABILITIES AND OSCILLATIONS IN SIMPLE-MODELS OF ELECTROCATALYTIC SURFACE-REACTIONS

被引：107

作者：

KOPER, MTM

SLUYTERS, JH

机构：

[1] Department of Electrochemistry, University of Utrecht, 3584 CH Utrecht

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1994年 / 371卷 / 1-2期

关键词：

D O I：

10.1016/0022-0728(93)03248-N

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Possible explanations for the occurrence of instabilities and oscillations in electrocatalytic reactions are studied for three different kinds of external control of the electrochemical cell: potentiostatic control, fixed-potential control in the case where account must be taken of the cell resistance or an external resistor and galvanostatic control. The relation of our models to existing models and experiments is discussed.

引用

页码：149 / 159

页数：11

共 43 条

[1] OBSERVATION OF SEVERAL DIFFERENT TEMPORAL PATTERNS IN THE OXIDATION OF FORMIC-ACID AT A ROTATING PLATINUM-DISK ELECTRODE IN AN ACIDIC MEDIUM [J].