1,3,5-TRIDEOXY-1,3,5-TRIS(2-HYDROXYBENZYL)AMINO)-CIS-INOSITOL, A NOVEL MULTIDENTATE LIGAND PROVIDING VARIOUS N,O COORDINATION SITES - STRUCTURE OF THE RHENIUM(V) COMPLEX

被引：19

作者：

HEGETSCHWEILER, K ^{[1
]}

EGLI, A ^{[1
]}

ALBERTO, R ^{[1
]}

SCHMALLE, HW ^{[1
]}

机构：

[1] UNIV ZURICH,INST ANORGAN CHEM,CH-8057 ZURICH,SWITZERLAND

来源：

INORGANIC CHEMISTRY | 1992年 / 31卷 / 20期

关键词：

D O I：

10.1021/ic00046a001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

1,3,5-Trideoxy- 1,3,5-tris((2-hydroxybenzyl)amino)cis-inositol (H3thci), a new type of a potentially hexadentate ligand providing various coordination sites, was prepared, and complex formation with Re(V) was investigated. The observed pentadentate coordination of thci demonstrated the affinity of Re(V) for O(oxo), nitrogen atoms in the cis position of O(oxo), and an oxygen atom in the trans position of O(oxo) in combination with a coordination number of 6.

引用

页码：4027 / 4028

页数：2

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