STEREOSELECTIVE CARBON-CARBON BOND FORMATION VIA ALLYLIC N-SULFONYLIMINIUM IONS

被引：38

作者：

HOPMAN, JCP ^{[1
]}

VANDENBERG, E ^{[1
]}

OLLERO, LO ^{[1
]}

HIEMSTRA, H ^{[1
]}

SPECKAMP, WN ^{[1
]}

机构：

[1] UNIV AMSTERDAM,AMSTERDAM INST MOLEC STUDIES,ORGAN CHEM LAB,1018 WS AMSTERDAM,NETHERLANDS

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 24期

关键词：

D O I：

10.1016/0040-4039(95)00748-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

N-Tosyl-6-alkoxy-2,6-dihydro-1H-pyridin-3-ones 1 were found to react stereoselectively with various nucleophiles under the influence of BF3 . OEt(2) yielding 2,6-cis-disubstituted dihydropyridinones.

引用

页码：4315 / 4318

页数：4

共 19 条

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