THEORETICAL EVIDENCE OF A SINGLET ALPHA-OXOCARBENE INTERMEDIATE IN THE RETRO-WOLFF REARRANGEMENT OF AZAFULVENONE

被引：8

作者：

NGUYEN, MT

HAJNAL, MR

VANQUICKENBORNE, LG

机构：

[1] Department of Chemistry, University of Leuven, B-3001 Leuven

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1994年 / 02期

关键词：

D O I：

10.1039/p29940000169

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Abh initio MO calculations at the CISDQ/6-31G(**) level suggest that the transformation of azafulvenone yielding isocyanovinyl ketene involves a singlet cyclic alpha-oxocarbene intermediate.

引用

页码：169 / 170

页数：2

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