HIGHLY REACTIVE DIALDEHYDES OF CELLULOSE AND ALPHA-CYCLODEXTRIN

被引：24

作者：

KOBAYASHI, M ^{[1
]}

SUZAWA, I ^{[1
]}

ICHISHIMA, E ^{[1
]}

机构：

[1] TOHOKU UNIV,FAC AGR,DEPT AGR CHEM,SENDAI,MIYAGI 981,JAPAN

来源：

AGRICULTURAL AND BIOLOGICAL CHEMISTRY | 1990年 / 54卷 / 07期

关键词：

D O I：

10.1080/00021369.1990.10870202

中图分类号：

S3 [农学（农艺学）];

学科分类号：

0901 ;

摘要：

Dialdehyde derivatives of cellulose (CE) and α-cyclodextrin (α-CD) were prepared by the periodate oxidation method. Linkage formation between cellulose dialdehyde (dial-CE) and bovine serum albumin (BSA) proceeded rapidly at pH 9.0 and gave a maximum yield at about 30 hr. Among the various amino compounds tested, ethylenediamine, hexylamine, hexamethylenediamine and BSA were bound effectively to the dial-CE in this order. As compared with the case of dial-CE, reactions between α-CD dialdehyde (dial-CD) and amino compounds proceeded rather slowly. Separation of dial-CD isomers linked with glycine by a DEAE-Sephacel column resulted in several peaks. However, the components of each fraction were not homogeneous. Reactions of dialdehyde derivatives with amino compounds were thought to produce a 4-oxa-azepine-type of complex. © 1990 by the Japan Society for Bioscience, Biotechnology, and Agrochemistry. All rights reserved.

引用

页码：1705 / 1709

页数：5

共 16 条

[1]

BOBBITT JM, 1956, ADV CARBOHYD CHEM, V11, P1

[2]

BRADFORD MM, 1976, ANAL BIOCHEM, V72, P248, DOI 10.1016/0003-2697(76)90527-3

[3] COLORIMETRIC METHOD FOR DETERMINATION OF SUGARS AND RELATED SUBSTANCES [J].

DUBOIS, M ;

GILLES, KA ;

HAMILTON, JK ;

REBERS, PA ;

SMITH, F .

ANALYTICAL CHEMISTRY, 1956, 28 (03) :350-356

[4]

FRENCH D, 1957, ADV CARBOHYD CHEM, V12, P189

[5] INACTIVATION OF PHOSPHOFRUCTOKINASE BY DIALDEHYDE-ATP [J].

GREGORY, MR ;

KAISER, ET .

ARCHIVES OF BIOCHEMISTRY AND BIOPHYSICS, 1979, 196 (01) :199-208

[6]

GUTHRIE RD, 1962, METHODS CARBOHYD CHE, V1, P435

[7] INTERACTION OF PHOSPHORYLASE-KINASE WITH THE 2',3'-DIALDEHYDE DERIVATIVE OF ADENOSINE-TRIPHOSPHATE .1. KINETICS OF INACTIVATION [J].

KING, MM ;

CARLSON, GM .

BIOCHEMISTRY, 1981, 20 (15) :4382-4387

[8] CYCLODEXTRIN DIALDEHYDE PREPARED BY PERIODATE-OXIDATION [J].

KOBAYASHI, M ;

URAYAMA, T ;

SUZAWA, I ;

TAKAGI, S ;

MATSUDA, K ;

ICHISHIMA, E .

AGRICULTURAL AND BIOLOGICAL CHEMISTRY, 1988, 52 (11) :2695-2702

[9] FLUORESCENT DERIVATIVES OF POLYSACCHARIDE DIALDEHYDE AS SUBSTRATES FOR GLUCANASES [J].

KOBAYASHI, M ;

URAYAMA, T ;

ICHISHIMA, E .

AGRICULTURAL AND BIOLOGICAL CHEMISTRY, 1990, 54 (07) :1711-1718

[10] INHIBITION OF ALPHA-AMYLASE AND PHOSPHORYLASES BY CYCLODEXTRIN DIALDEHYDE [J].

KOBAYASHI, M ;

TAKAGI, S ;

MATSUDA, K ;

ICHISHIMA, E .

AGRICULTURAL AND BIOLOGICAL CHEMISTRY, 1988, 52 (11) :2703-2708

← 1 2 →