REMARKABLE EFFECT OF ALKYLBENZENES AS SOLVENTS IN ENANTIOSELECTIVE ALKYLATION OF N-DIPHENYLPHOSPHINOYLIMINES WITH DIETHYLZINC USING POLYSTYRENE SUPPORTED EPHEDRINE

被引：36

作者：

SOAI, K

SUZUKI, T

SHONO, T

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 03期

关键词：

D O I：

10.1039/c39940000317

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Diethylzinc adds to N-diphenylphosphinoylimines highly enantioselectively using chiral ephedrine supported on polystyrene, the enantioselectivities of the reaction in alkylbenzenes are much higher than those in individual aromatic (benzene) and aliphatic (hexane) hydrocarbons.

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页码：317 / 318

页数：2

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