ARGENTOTROPISM IN (PENTAMETHYLCYCLOPENTADIENYL)IRIDIUM COMPLEXES WITH PYRAZOLE LIGANDS - MULTINUCLEAR DNMR EXPERIMENTS

被引：26

作者：

CARMONA, D

ORO, LA

LAMATA, MP

JIMENO, ML

ELGUERO, J

BELGUISE, A

LUX, P

机构：

[1] UNIV ZARAGOZA,CSIC,ESCUELA UNIV INGN TECN IND,INST CIENCIA MAT ARAGON,E-50009 ZARAGOZA,SPAIN

[2] CSIC,INST QUIM MED,E-28006 MADRID,SPAIN

[3] BRUICER SPECTROSPIN,APPLICAT LAB,F-67160 WISSEMBOURG,FRANCE

来源：

INORGANIC CHEMISTRY | 1994年 / 33卷 / 10期

关键词：

D O I：

10.1021/ic00088a022

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The dynamic behavior of the heterobimetallic compounds [(eta5-C5Me5)Ir(pz)3Ag(PPh3)] (2), [(eta5-C5Me5)Ir(mu-pz)3{Ag(PPh3)}2]BF4 (3), [(eta5-C5Me5)Ir(pz)2 PPh3] (4), and [(eta5-C5Me5)Ir(PPh3)(mu-pz)2Ag(PPh3)]BF4 (5) has been studied by multinuclear (H-1, C-13, N-15, P-31, and Ag-109) NMR. The results demonstrate that argentotiropism accounts for the observed spectra of compounds 2 (DELTAH = 8.3 kcal mol-1, DELTAS = -13 eu) and 3 (DELTAH = 7.6 kcal mol-1, DELTAS = -20 eu); in the case of compound 4, the dynamic behavior is due to a slow rotation about the P-Ir bond, and for compound 5, the dynamic behavior corresponds to a flipping of the central heteroring Ir(N)4Ag. Several new heteronuclear coupling constants have been determined, some of them [such as 1J(P-31-Ag-107(109)] being related to the structure and dynamical properties of the complex.

引用

页码：2196 / 2203

页数：8

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