METATHESIS OF PHOSPHORUS-CONTAINING OLEFINS CATALYZED BY A CYCLOMETALATED ARYLOXO(CHLORO)NEOPENTYLIDENE-TUNGSTEN COMPLEX

被引：39

作者：

LECONTE, M ^{[1
]}

JOURDAN, I ^{[1
]}

PAGANO, S ^{[1
]}

LEFEBVRE, F ^{[1
]}

BASSET, JM ^{[1
]}

机构：

[1] LAB CHIM ORGANOMET SURFACE,CNRS,UMR CPE 9986,F-69626 VILLEURBANNE,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 08期

关键词：

D O I：

10.1039/c39950000857

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A cyclometallated O,O'-diphenyl aryloxy(chloro)neopentylidene-tungsten complex W(OAr)(OAr)(CHCMe(3))Cl(OEt(2)) 1 is able to carry out metathesis of phosphorous containing olefins; diallylphenyl phosphane is metathetized intramolecularly to give the corresponding phospholene derivative 2 and allyldiphenyl phosphane gives the corresponding bisphosphane 3.

引用

页码：857 / 858

页数：2

共 9 条

[1] INFLUENCE OF STERIC CROWDING AT THE HETEROATOM ON THE METATHESIS OF FUNCTIONALIZED OLEFINS - THE POLYMERIZATION OF ALKYLTHIOCYCLOOCTENES CATALYZED BY A METALLACYCLIC ARYLOXO(CHLORO)NEOPENTYLIDENETUNGSTEN COMPLEX
COUTURIER, JL
LECONTE, M
BASSET, JM
OLLIVIER, J
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 451 (1-2) : C7 - C9
[2] A CYCLOMETALATED ARYLOXY(CHLORO)NEOPENTYLIDENETUNGSTEN COMPLEX - A HIGHLY-ACTIVE AND STEREOSELECTIVE CATALYST FOR THE METATHESIS OF CIS-2-PENTENE, AND TRANS-2-PENTENE, NORBORNENE, 1-METHYL-NORBORNENE, AND ETHYL OLEATE
COUTURIER, JL
PAILLET, C
LECONTE, M
BASSET, JM
WEISS, K
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1992, 31 (05): : 628 - 631
[3] COUTURIER JL, 1993, ANGEW CHEM INT EDIT, V32, P112, DOI 10.1002/anie.199301121
[4] DESCOTES G, 1994, TETRAHEDRON LETT, V40, P7379
[5] SYNTHESIS OF NITROGEN-HETEROCYCLES VIA CATALYTIC RING-CLOSING METATHESIS OF DIENES
FU, GC
GRUBBS, RH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (18) : 7324 - 7325
[6] THE APPLICATION OF CATALYTIC RING-CLOSING OLEFIN METATHESIS TO THE SYNTHESIS OF UNSATURATED OXYGEN HETEROCYCLES
FU, GC
GRUBBS, RH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (13) : 5426 - 5427
[7] RING-OPENING POLYMERIZATION OF NORBORNENE SUBSTITUTED WITH AMINE AND AMMONIUM GROUPS
LARROCHE, C
LAVAL, JP
LATTES, A
BASSET, JM
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1984, 49 (11) : 1886 - 1890
[8] ACYCLIC DIENE METATHESIS (ADMET) POLYMERIZATION - SYNTHESIS OF UNSATURATED POLYTHIOETHERS
OGARA, JE
PORTMESS, JD
WAGENER, KB
[J]. MACROMOLECULES, 1993, 26 (11) : 2837 - 2841
[9] SIBEIJN M, 1991, APPL CATAL, V67, P279

← 1 →