THE SCOPE AND LIMITATIONS OF LIQUID-CRYSTALLINE BEHAVIOR IN MONOSACCHARIDE AMPHIPHILES - COMPARISON OF THE THERMAL-BEHAVIOR OF SEVERAL HOMOLOGOUS SERIES OF D-GLUCOSE DERIVED COMPOUNDS WITH AN AMINO-LINKED ALKYL CHAIN

被引:46
作者
VANDOREN, HA [1 ]
VANDERGEEST, R [1 ]
DERUIJTER, CF [1 ]
KELLOGG, RM [1 ]
WYNBERG, H [1 ]
机构
[1] STATE UNIV GRONINGEN,DEPT ORGAN CHEM,9747 AG GRONINGEN,NETHERLANDS
关键词
D O I
10.1080/02678299008047334
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A short review of the scope and limitations of liquid-crystalline behaviour in carbohydrate derivatives is presented. In order to investigate the influence of structure variations on the thermal behaviour of monosaccharide amphiphiles, six homologous series of D-glucose and 2-deoxy-D-glucose derivatives with an aminolinked n-alkyl chain were prepared. The observed thermal behaviour could be readily explained with the aid of a refinement of the qualitative model that was presented earlier [1]. All compounds were found to be mesogenic, and the observed mesophase was smectic Ad (i.e. a partially overlapping bilayer structure) in all cases. © 1990 Taylor & Francis Group, LLC.
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页码:109 / 121
页数:13
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