ORGANOMETAL LEWIS-ACIDS .51. REACTIVITY OF THE ORGANOMETAL LEWIS-ACIDS (OC)(4)RE(OET(2))FBF3 AND (OC)(2)(PPH(3))(2)RU(FBF3)(2)

被引：11

作者：

LIPPMANN, E ^{[1
]}

KRAMER, R ^{[1
]}

BECK, W ^{[1
]}

机构：

[1] UNIV MUNICH,INST ANORGAN CHEM,D-80333 MUNICH,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 466卷 / 1-2期

关键词：

RUTHENIUM; RHENIUM; PHOSPHORUS; TETRAFLUOROBORATE;

D O I：

10.1016/0022-328X(94)88043-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex [(OC)(4)Re(OH2)(2)](+) reacts with oxalate and squarate to give the complexes [(OC)(4)Re(OH2)2]C2O4 (1) and [(OC)(4)Re(OH2)(2)]C4O4 (2). The reaction of (OC)(2)(PPh(3))(2)Ru(FBF3)(2) with potassium salts of cu-aminoacids (glycine, L-alanine, L-phenylalanine) yields cationic ruthenium complexes with chelating aminoacidates (3-5). With acetylacetonate the complex [(OC)(2)(PPh(3))(2)Ru(acac)I[BF4] (16) is obtained. Nitriles and isonitriles give the complexes [(OC)(4)Re(N=C-R)(2)][BF4] (6: R = Me; 7: R = CH(2)CO(2)Et), [(OC)(2)(PPh(3))(2)Ru(N=C-R)(2)I[BF4](2) (8: R = Me, 9: R = p-C(6)H(4)OMe), [(OC)(4) Re(C=N-R)(2)][BF4] (10: R = (CH2)(3)Me; 11: R = CH(2)CO(2)Et) and [(OC)(2)(PPh(3))(2)Ru(C=N-R)2][BF4](2) (12: R = CH(2)CO(2)Et; 13: R = C6H11), respectively. With thioethers (OC)(4)Re(OEt(2))FBF3 forms the complexes [(OC)(4)Re(Ph-S-CH2-S-Ph)][BF4] (14) and [(OC)(4) Re(HO-(CH2)(2)-S(CH2)(2)-S-(CH2)(2)OH)][BF4] (15).

引用

页码：167 / 174

页数：8

共 42 条

[1] REACTIONS OF HEXACARBONYLRHENIUM(I) PERCHLORATE WITH PHOSPHINES AND OTHER LIGANDS [J].