MICROSCOPIC AND MACROSCOPIC SOLVATION OF AROMATIC-MOLECULES IN ALIPHATIC-HYDROCARBONS

被引：17

作者：

BENHORIN, N

EVEN, U

JORTNER, J

机构：

[1] School of Chemistry, Tel-Aviv University

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 177卷 / 02期

关键词：

D O I：

10.1016/0009-2614(91)90061-D

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The S0 --> S1 transition of heteroclusters of anthracene and tetracene with alkanes was interrogated by resonant two-colour two-photon ionization. The microscopic spectral shifts of tetracene heptane(n) (n = 1-12) clusters converge for n > 7 to those of the tetracene-heptane solution spectra, documenting a spectroscopic manifestation of the gradual "transition" from finite to infinite systems.

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页码：153 / 160

页数：8

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