ULTRASENSITIVE DETECTION OF CHLORINATED HYDROCARBONS BY RESONANCE IONIZATION

被引：31

作者：

COOL, TA

WILLIAMS, BA

机构：

[1] School of Annlied and Engineering Physics, Cornell University, Ithaca

来源：

COMBUSTION SCIENCE AND TECHNOLOGY | 1992年 / 82卷 / 1-6期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1080/00102209208951813

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Resonance-enhanced multiphoton ionization (REMPI) spectroscopic techniques are under development for the continuous monitoring of toxic emissions from municipal and hazardous waste incinerators. REMPI detection schemes and detection limit data for monitoring the chloroethylenes at part-per-billion concentrations are presented. The high sensitivity and selectivity demonstrated for the detection of tetrachloroethylene (C2Cl4) make it a particularly attractive surrogate for monitoring the presence of numerous other chlorinated hydrocarbon species found in incineration stack gases. © 1992, Taylor & Francis Group, LLC. All rights reserved.

引用

收藏

页码：67 / 85

页数：19

相关论文

共 27 条

[1] MULTI-PHOTON IONIZATION IN THE MASS-SPECTROMETRY OF POLYATOMIC-MOLECULES - CROSS-SECTIONS [J].

BOESL, U ;

NEUSSER, HJ ;

SCHLAG, EW .

CHEMICAL PHYSICS, 1981, 55 (02) :193-204

[2] MOLECULAR-BEAM MASS SPECTROSCOPIC STUDY OF TRICHLOROETHYLENE FLAMES [J].

CHANG, WD ;

KARRA, SB ;

SENKAN, SM .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1986, 20 (12) :1243-1248

[3] OPTICAL DIAGNOSTICS IN CHC COMBUSTION [J].

COOL, TA ;

WILLIAMS, BA .

HAZARDOUS WASTE & HAZARDOUS MATERIALS, 1990, 7 (01) :21-39

[4] THE VIABILITY OF USING SURROGATE COMPOUNDS FOR MONITORING THE EFFECTIVENESS OF INCINERATION SYSTEMS [J].

DELLINGER, B ;

HALL, DL .

JOURNAL OF THE AIR POLLUTION CONTROL ASSOCIATION, 1986, 36 (02) :179-183

[5]

DELLINGER B, 1987, JAPCA J AIR WASTE MA, V37, P1019, DOI 10.1080/08940630.1987.10466293

[6] A MODEL FOR MULTI-PHOTON IONIZATION MASS-SPECTROSCOPY WITH APPLICATION TO BENZENE [J].

DIETZ, W ;

NEUSSER, HJ ;

BOESL, U ;

SCHLAG, EW ;

LIN, SH .

CHEMICAL PHYSICS, 1982, 66 (1-2) :105-127

[7] METHANE, HYDROGEN-CHLORIDE AND OXYGEN FORM A WIDE-RANGE OF CHLORINATED ORGANIC-SPECIES IN THE TEMPERATURE-RANGE 400-DEGREES-C-950-DEGREES-C [J].

EKLUND, G ;

PEDERSEN, JR ;

STROMBERG, B .

CHEMOSPHERE, 1988, 17 (03) :575-586

[8] LABORATORY INVESTIGATION OF THERMAL-DEGRADATION OF A MIXTURE OF HAZARDOUS ORGANIC-COMPOUNDS .1. [J].

GRAHAM, JL ;

HALL, DL ;

DELLINGER, B .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1986, 20 (07) :703-710

[9] DIRECT CALIBRATION OF LASER WAVELENGTH AND BANDWIDTH USING OPTOGALVANIC EFFECT IN HOLLOW-CATHODE LAMPS [J].

KING, DS ;

SCHENCK, PK ;

SMYTH, KC ;

TRAVIS, JC .

APPLIED OPTICS, 1977, 16 (10) :2617-2619

[10] EVALUATION OF CONTINUOUS PERFORMANCE MONITORING TECHNIQUES FOR HAZARDOUS-WASTE INCINERATORS [J].

LAFOND, RK ;

KRAMLICH, JC ;

SEEKER, WR ;

SAMUELSEN, GS .

JOURNAL OF THE AIR POLLUTION CONTROL ASSOCIATION, 1985, 35 (06) :658-663