PHOTOCHEMICAL OXIDATION OF HYDROCARBONS BY A VANADIUM(V) PEROXO COMPLEX

被引：16

作者：

ATTANASIO, D ^{[1
]}

SUBER, L ^{[1
]}

SHULPIN, GB ^{[1
]}

机构：

[1] NN SEMENOV CHEM PHYS INST,117977 MOSCOW,RUSSIA

来源：

BULLETIN OF THE RUSSIAN ACADEMY OF SCIENCES-DIVISION OF CHEMICAL SCIENCE | 1992年 / 41卷 / 08期

关键词：

OXIDATION; HYDROCARBONS; PHOTOCHEMISTRY; PEROXO COMPLEXES; AND VANADIUM;

D O I：

10.1007/BF00864356

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The oxidation of alkanes and benzene by VO(O2)L.2H2O (L = 2-picolinate) in acetonitrile is accelerated upon irradiation with visible and, especially, UV light. Cyclohexyl hydroperoxide, cyclohexanol, and cyclohexanone in approximately 2:1:1 ratio are formed from cyclohexane both in the dark and photochemical reactions. Benzene is oxidized to phenol.

引用

页码：1502 / 1504

页数：3

共 22 条

[1] AEROBIC PHOTOOXIDATION OF SUBSTITUTED BENZENES CATALYZED BY THE TUNGSTEN ISOPOLYANION [W10O32]4- [J].