DIRECT MODIFICATION OF ORIENTATIONAL OPACITY FUNCTION FOR THE CF3H+AR(P-3) REACTION USING INFORMATION ENTROPY

被引：6

作者：

FUKUNISHI, Y ^{[1
]}

KASAI, T ^{[1
]}

KUWATA, K ^{[1
]}

机构：

[1] OSAKA UNIV,FAC SCI,DEPT CHEM,TOYONAKA,OSAKA 560,JAPAN

来源：

CHEMICAL PHYSICS | 1993年 / 177卷 / 01期

关键词：

D O I：

10.1016/0301-0104(93)80179-D

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A direct modification of the orientational opacity function using information entropy is presented, in which the experimental uncertainty is directly taken into account in the process of maximizing the information entropy. Since the present modification treats the experimental error directly in the computational procedure, it differs from the Engel-Levine method, which is a general modification. The present method was applied to the orientational dependence of the CF3* radical formation in the reaction of CF3H with the Ar(3P) atom. The result approved the presence of the three reactive sites for the CF3H reaction and showed the usefulness of the present method for improving the reliability of the opacity function.

引用

页码：85 / 90

页数：6

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