[1,3]-SIGMATROPIC REARRANGEMENT OF 1,3,5-TRIPHOSPHABICYCLO[2.1.0]PENT-2-ENE

被引：15

作者：

BACHRACH, SM ^{[1
]}

CALIMAN, V ^{[1
]}

NIXON, JF ^{[1
]}

机构：

[1] UNIV SUSSEX,SCH CHEM & MOLEC SCI,BRIGHTON BN1 9QJ,E SUSSEX,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 23期

关键词：

D O I：

10.1039/c39950002395

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The activation barrier for the [1,3]-phosphorus migration in the title compound is estimated (MP4SDTQ/6-31 G*//MP2/6-31 G* + ZPE) to be 11.62 kcal mol(-1) (1 cal = 4.184 J), which is considerably smaller than the barrier (31.13 kcal mol(-1)) for [1,3]-carbon migration in the corresponding hydrocarbon.

引用

页码：2395 / 2396

页数：2

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