ADDITION OF SULFINYLATED AND SULFONYLATED CARBON CENTERED RADICALS TO ALKENES AND ENOLETHERS

被引：43

作者：

RENAUD, P

机构：

[1] Université de Lausanne, Institut de Chimie Organique, CH-1005 Lausanne

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 32期

关键词：

D O I：

10.1016/S0040-4039(00)97686-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

(p-Tolylsulfonyl)- and (p-tolylsulfinyl)methyl radicals reacted with electron rich olefins like vinylsilane, enolethers and silylenolethers in the presence of Bu3SnH to give addition products. Cyclization of sulfonylated and sulfinylated radicals proceeded in good yield and high trans stereoselectivity in the case of enolethers. © 1990.

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页码：4601 / 4604

页数：4

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