FLASH VACUUM PYROLYSIS OF SULFONYL STABILIZED PHOSPHORUS YLIDES - GENERATION AND REACTIVITY OF SULFONYL CARBENES

被引：10

作者：

AITKEN, RA

DRYSDALE, MJ

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 07期

关键词：

D O I：

10.1039/c39910000512

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Thermal decomposition of arylmethylsulphonylalkylidenetriphenylphosphoranes results in loss of Ph3P and SO2 to give alkenes and in some cases products derived from benzylic radicals, the products are explained by a mechanism involving sulphonyl carbenes.

引用

页码：512 / 513

页数：2

共 14 条

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