EVIDENCE FOR A TEMPLATE EFFECT IN CONTROL OF ORGANIC-INORGANIC HYBRID SOLID FORMATION BY INTERMOLECULAR INTERACTIONS

被引：39

作者：

CORRIU, RJP

MOREAU, JJE

THEPOT, P

MAN, MWC

机构：

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1994年 / 4卷 / 06期

关键词：

D O I：

10.1039/jm9940400987

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Very fast gelation was observed in the sol-gel polycondensation of olefinic trialkoxysilanes when performed in the presence of catalytic amounts of palladium complexes. The palladium activation is proposed as proceeding by a template effect; the condensation occurred in an intramolecular manner within the coordination sphere of the metal.

引用

页码：987 / 989

页数：3

共 34 条

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