TIME SCALES FOR MOLECULAR PHOTODISSOCIATION

被引：24

作者：

BESWICK, JA ^{[1
]}

JORTNER, J ^{[1
]}

机构：

[1] TEL AVIV UNIV, SCH CHEM, IL-69978 TEL AVIV, ISRAEL

来源：

CHEMICAL PHYSICS LETTERS | 1990年 / 168卷 / 3-4期

关键词：

D O I：

10.1016/0009-2614(90)85604-B

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Direct dissociation dynamics is characterized by two distinct time scales, that is, the decay time of the autocorrelation function of the initial nuclear wavepacket τd (≈10-14-10-15 s) and the bond rupture time τb (∼10-13 s). τd and τb are analogous to T2-type dephasing and to T1-type level depletion processes, respectively. © 1990.

引用

页码：246 / 248

页数：3

共 45 条

[1] Ashfold M. N. R., 1987, ADV GAS PHASE PHOTOC
[2] VIBRATIONALLY EXCITED CYANOGEN RADICALS PRODUCED IN FLASH PHOTOLYSIS OF CYANOGEN AND CYANOGEN HALIDES
BASCO, N
NORRISH, RGW
NICHOLAS, JE
VICKERS, WHJ
[J]. PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1963, 272 (1348) : 147 - +
[3] VIBRATIONALLY EXCITED NITRIC OXIDE PRODUCED IN FLASH PHOTOLYSIS OF NITROSYL HALIDES
BASCO, N
NORRISH, RGW
[J]. PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1962, 268 (1334): : 291 - &
[4] BERJOT M, 1971, OPT COMMUN, V4, P246
[5] BERJOT M, 1971, OPT COMMUN, V4, P117
[6] FEMTOSECOND REAL-TIME PROBING OF REACTIONS .3. INVERSION TO THE POTENTIAL FROM FEMTOSECOND TRANSITION-STATE SPECTROSCOPY EXPERIMENTS
BERNSTEIN, RB
ZEWAIL, AH
[J]. JOURNAL OF CHEMICAL PHYSICS, 1989, 90 (02) : 829 - 842
[7] BERSOHN R, 1973, ISRAEL J CHEM, V11, P675
[8] TIME-DEPENDENT ABSORPTION OF FRAGMENTS DURING DISSOCIATION
BERSOHN, R
ZEWAIL, AH
[J]. BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1988, 92 (03): : 373 - 378
[9] BERSOHN R, 1969, ADV CHEM PHYS, V16, P80
[10] TRIATOMIC PHOTOFRAGMENT SPECTRA .2. ANGULAR-DISTRIBUTIONS FROM NO2 PHOTODISSOCIATION
BUSCH, GE
WILSON, KR
[J]. JOURNAL OF CHEMICAL PHYSICS, 1972, 56 (07) : 3638 - +

← 1 2 3 4 5 →