UNIFIED VIEW OF TRANSPORT PHENOMENA BASED ON THE GENERALIZED BRACKET FORMULATION

被引:31
作者
EDWARDS, BJ
BERIS, AN
机构
[1] UNIV DELAWARE,DEPT CHEM ENGN,NEWARK,DE 19716
[2] UNIV DELAWARE,CTR COMPOSITE MAT,NEWARK,DE 19716
关键词
D O I
10.1021/ie00053a009
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The Hamiltonian formulation of equations in continuum mechanics through generalized brackets is presented here in order to demonstrate the inherent structure and similarity between a variety of transport phenomena. The bracket formulation presented in this paper is based upon the Poisson bracket description of continuous systems and the entropy dissipation postulated in irreversible thermodynamics. This general formulation is presented for both single-component and multicomponent systems, as well as for systems with internal structure, for example, viscoelastic fluids. Thus, in addition to providing an alternative formulation for transport phenomena (of value for possible new numerical schemes), this paper represents the initial stages of a generalization of nonequilibrium thermodynamics to complex media (i.e., materials with internal structure), which has never been accomplished to date in a fully satisfactory manner using traditional approaches.
引用
收藏
页码:873 / 881
页数:9
相关论文
共 26 条
[1]   NON-EQUILIBRIUM THERMODYNAMICS OF NON-LINEAR EQUATIONS OF CHEMICAL-KINETICS [J].
BATAILLE, J ;
EDELEN, DGB ;
KESTIN, J .
JOURNAL OF NON-EQUILIBRIUM THERMODYNAMICS, 1978, 3 (03) :153-168
[2]   POISSON BRACKET FORMULATION OF VISCOELASTIC FLOW EQUATIONS OF DIFFERENTIAL TYPE - A UNIFIED APPROACH [J].
BERIS, AN ;
EDWARDS, BJ .
JOURNAL OF RHEOLOGY, 1990, 34 (04) :503-538
[3]   POISSON BRACKET FORMULATION OF INCOMPRESSIBLE-FLOW EQUATIONS IN CONTINUUM-MECHANICS [J].
BERIS, AN ;
EDWARDS, BJ .
JOURNAL OF RHEOLOGY, 1990, 34 (01) :55-78
[4]  
Bird R.B., 2007, TRANSPORT PHENOMENA
[5]  
Callen HB., 1960, THERMODYNAMICS
[6]   POISSON BRACKETS IN CONDENSED MATTER PHYSICS [J].
DZYALOSHINSKII, IE ;
VOLOVICK, GE .
ANNALS OF PHYSICS, 1980, 125 (01) :67-97
[7]   GENERALIZED CONSTITUTIVE EQUATION FOR POLYMERIC LIQUID-CRYSTALS .1. MODEL FORMULATION USING THE HAMILTONIAN (POISSON BRACKET) FORMULATION [J].
EDWARDS, BJ ;
BERIS, AN ;
GRMELA, M .
JOURNAL OF NON-NEWTONIAN FLUID MECHANICS, 1990, 35 (01) :51-72
[8]  
EDWARDS BJ, 1991, IN PRESS J PHYS A
[9]  
Forland K., 1988, IRREVERSIBLE THERMOD
[10]   BRACKET FORMULATION OF DIFFUSION-CONVECTION EQUATIONS [J].
GRMELA, M .
PHYSICA D-NONLINEAR PHENOMENA, 1986, 21 (2-3) :179-212