MONOTERPENE DIOL, IRIDOID GLUCOSIDE AND DIBENZO-ALPHA-PYRONE FROM ANTHOCLEISTA-DJALONENSIS

被引:52
作者
ONOCHA, PA [1 ]
OKORIE, DA [1 ]
CONNOLLY, JD [1 ]
ROYCROFT, DS [1 ]
机构
[1] UNIV GLASGOW,DEPT CHEM,GLASGOW G12 8QQ,LANARK,SCOTLAND
关键词
ANTHOCLEISTA DJALONENSIS; LOGANIACEAE; DJALONENOSIDE; DJALONENSONE; DJALONENOL; DIBENZO-ALPHA-PYRONE;
D O I
10.1016/0031-9422(95)00121-M
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 [生物化学与分子生物学]; 081704 [应用化学];
摘要
Anthocleista djalonensis has provided a new monoterpene diol, djalonenol, as well as the known iridoid glucoside djalonenoside (also sweroside). Also isolated for the first time from a plant source is a dibenzo-alpha-pyrone-djalonensone, previously identified as a fungal metabolite. The structure of the new compound was elucidated on the basis of its chemical and spectral data as tetrahydro-3-hydroxy hydroxymethylene-4-(3-hydroxymethylene prop-1-ene)-2H-pyran-2-one.
引用
收藏
页码:1183 / 1189
页数:7
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