HYDROCARBON-BRIDGED METAL-COMPLEXES .22. ADDITION OF ANIONIC FISCHER CARBENE COMPLEXES TO COORDINATED UNSATURATED-HYDROCARBONS WITH C-C COUPLING

被引：25

作者：

BREIMAIR, J ^{[1
]}

WEIDMANN, T ^{[1
]}

WAGNER, B ^{[1
]}

BECK, W ^{[1
]}

机构：

[1] UNIV MUNICH,INST ANORGAN CHEM,MEISERSTR 1,W-8000 MUNICH 2,GERMANY

来源：

CHEMISCHE BERICHTE | 1991年 / 124卷 / 11期

关键词：

FISCHER CARBENE COMPLEXES; ANIONIC; CARBENE; METHOXY(PENTACARBONYLRHENIOPROPYL); CHROMIUM COMPLEXES; MOLYBDENUM COMPLEXES; TUNGSTEN COMPLEXES; RHENIUM COMPLEXES;

D O I：

10.1002/cber.19911241110

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The addition of [(OC)5MC(OMe)CH2]- (M = Cr,W) to the cationic complexes [(OC)5Re(C2H4)]+ and [(OC)3M' (eta-7-C7H7)]+ (M' = Cr, Mo) affords the bimetallic hydrocarbon-bridged complexes (OC)5M = C(OMe)CH2CH2CH2Re(CO)5 (1) and (OC)5M = C(OMe)CH2C7H7 - eta-6 - M'(CO)3 (2), respectively. The structures of 1a and 2d have been determined by X-ray diffraction.

引用

页码：2431 / 2434

页数：4

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