FLOW ORIENTATION IN LANGMUIR-BLODGETT-FILMS OF A CHARGE-TRANSFER COMPLEX (TMTTF)3(C14TCNQ)2

被引：13

作者：

IKEGAMI, K ^{[1
]}

KURODA, S ^{[1
]}

TABE, Y ^{[1
]}

SAITO, K ^{[1
]}

SUGI, M ^{[1
]}

MATSUMOTO, M ^{[1
]}

NAKAMURA, T ^{[1
]}

KAWABATA, Y ^{[1
]}

机构：

[1] NATL CHEM LAB IND,TSUKUBA,IBARAKI 305,JAPAN

来源：

JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS | 1992年 / 31卷 / 04期

关键词：

LB FILMS; CHARGE-TRANSFER COMPLEX; ESR; POLARIZED OPTICAL SPECTROSCOPY; FLOW ORIENTATION; COMPRESSION ORIENTATION; MOLECULAR ORIENTATION;

D O I：

10.1143/JJAP.31.1206

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

The occurrence of flow orientation during the deposition of Langmuir-Blodgett films of (TMTTF)3(C14TCNQ)2 is shown through studies of in-plane molecular orientation in films deposited by two types of the vertical dipping method, with the substrates parallel and perpendicular to the barrier, using ESR and polarized UV-visible spectroscopies. Larger in-plane anisotropy is observed toward the edge of the substrates, which is consistent with the prediction of the recent theory of flow orientation during the deposition process. Furthermore, in-plane anisotropy in the films deposited by the horizontal lifting method is detected, suggesting the existence of a compression orientation at the air-water interface.

引用

页码：1206 / 1212

页数：7

共 22 条

[1] SPIN-RESONANCE OF TETRAMETHYLTETRATHIAFULVALENE TETRACYANOQUINODIMETHANE - COMPARISON WITH TETRATHIAFULVALENE TETRACYANOQUINODIMETHANE [J].