REARRANGEMENTS FROM THE REACTIONS OF SILENES WITH TRIMETHYLSILYLKETENE

被引：5

作者：

BROOK, AG

BAUMEGGER, A

机构：

[1] Lash Miller Chemical Laboratories, University of Toronto, Toronto

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 446卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)80055-G

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Silenes of the family (Me3Si)2Si=C(OSiMe3)R (R = Ad, (t)Bu) react with Me3SiCH=C=O to give non-cyclic acylsilane adducts which result from major skeletal rearrangement of a postulated [2+2] initial adduct.

引用

页码：C9 / C11

页数：3

共 9 条

[1] REACTIONS OF STABLE SILENES WITH DIENES AND ALKENES - [2+2], [2+4], AND ENE REACTIONS [J].

BROOK, AG ;

VORSPOHL, K ;

FORD, RR ;

HESSE, M ;

CHATTERTON, WJ .

ORGANOMETALLICS, 1987, 6 (10) :2128-2137

[2] REACTIONS OF SILENES WITH ALPHA,BETA-UNSATURATED ALDEHYDES AND KETONES [J].

BROOK, AG ;

HU, SS ;

CHATTERTON, WJ ;

LOUGH, AJ .

ORGANOMETALLICS, 1991, 10 (08) :2752-2757

[3] CYCLOADDITION AND OTHER REACTIONS OF SILENES WITH ALPHA,BETA-UNSATURATED ESTERS [J].

BROOK, AG ;

HU, SS ;

SAXENA, AK ;

LOUGH, AJ .

ORGANOMETALLICS, 1991, 10 (08) :2758-2767

[4] SI-29 NMR-STUDIES OF RELATIVELY STABLE SILAETHYLENES [J].

BROOK, AG ;

NYBURG, SC ;

REYNOLDS, WF ;

POON, YC ;

CHANG, YM ;

LEE, JS ;

PICARD, JP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (22) :6750-6752

[5] C-13 AND SI-29 CHEMICAL-SHIFTS AND COUPLING-CONSTANTS INVOLVING TRIS(TRIMETHYLSILYL)SILYL SYSTEMS [J].

BROOK, AG ;

ABDESAKEN, F ;

GUTEKUNST, G ;

PLAVAC, N .

ORGANOMETALLICS, 1982, 1 (07) :994-998

[6] 1,2-SILOXETANES - FORMATION, STRUCTURE, AND REARRANGEMENTS [J].

BROOK, AG ;

CHATTERTON, WJ ;

SAWYER, JF ;

HUGHES, DW ;

VORSPOHL, K .

ORGANOMETALLICS, 1987, 6 (06) :1246-1256

[7] A NOVEL STEREOCHEMICAL REARRANGEMENT PROCESS FOR AN ISOMER OF TRIMETHYLSILICON ACETYLACETONATE, A SILYL ENOL ETHER [J].

HOWE, JJ ;

PINNAVAI.TJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (19) :5378-&

[8] ATTACHED PROTON TEST FOR C-13 NMR [J].

PATT, SL ;

SHOOLERY, JN .

JOURNAL OF MAGNETIC RESONANCE, 1982, 46 (03) :535-539

[9] STEREOCHEMICAL STUDIES OF DEGENERATE SILYL REARRANGEMENTS - STEREOSPECIFICITY OF TROPOLONE AND ACETYLACETONE TRIALKYSILYL ETHER REARRANGEMENTS [J].

REICH, HJ ;

MURCIA, DA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (10) :3418-3420

← 1 →