CATIONIC, NEUTRAL, AND ANIONIC ORGANOALUMINUM SPECIES IN [ALME(2)(18-CROWN-6)ALME(2)X][ALMEX(3)] (X=CL, I)

被引：9

作者：

ATWOOD, JL

BOTT, SG

HARVEY, S

JUNK, PC

机构：

[1] Department of Chemistry, University of Missouri—Columbia, Columbia

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 11期

关键词：

D O I：

10.1021/om00023a010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

18-crown-6 reacts with AlX(3) (X = Cl, 1, X = I, 2) in an ex cess of AlMe(3) in toluene to form the liquid clathrate species [AlMe(2)(18-crown-6)AlMe(2)X][AlMeX(3)]. The AlMe(2)(+) ion is coordinated to the interior of the macrocycle, while the neutral species is coordinated to the exterior, via an inverted crown oxygen atom.

引用

页码：4151 / 4152

页数：2

共 21 条

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