METALLIZATION OF POLYTHIOPHENES .3. INTERACTION OF VAPOR-DEPOSITED CU AND NI WITH POLY(3-OCTYLOXY-METHYLTHIOPHENE) (P3O4MT)

被引：10

作者：

LACHKAR, A

SELMANI, A

SACHER, E

LECLERC, M

机构：

[1] ECOLE POLYTECH,DEPT GENIE PHYS,MONTREAL,PQ H3C 3A7,CANADA

[2] ECOLE POLYTECH,DEPT CHIM,MONTREAL,PQ H3C 3J7,CANADA

来源：

SYNTHETIC METALS | 1995年 / 72卷 / 01期

基金：

加拿大自然科学与工程研究理事会;

关键词：

METALLIZATION; POLYTHIOPHENE; DEPOSITION; POLY(3-OCTYLOXY-METHYLTHIOPHENE);

D O I：

10.1016/0379-6779(94)02330-2

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

We have investigated the interactions of vapor-deposited Cu and Ni with poly(3-octyloxy-4-methylthiophene) (P3O4MT). Charge transfer processes between the atoms were analyzed using X-ray photoelectron spectroscopy (XPS). The interactions of P3O4MT with Cu and Ni were found to modify the structure of the conjugated polymer: strong S-metal and O-metal bonds were formed. At higher coverages, the two metals also reacted with some C atoms, forming carbide. The extent of interaction of Cu with P3O4MT was less than that of Ni.

引用

页码：81 / 88

页数：8

共 25 条

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