NEW SYNTHESIS OF MACROCYCLIC-COMPOUNDS FROM TETRAAZAPENTALENE DERIVATIVES WITH THE HYPERVALENT SULFUR

被引：7

作者：

MATSUMURA, N

HIRASE, R

MORI, O

INOUE, H

机构：

来源：

CHEMISTRY LETTERS | 1993年 / 05期

关键词：

D O I：

10.1246/cl.1993.865

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

2,3-Bis[(p-isothiocyanatomethylphenyl)methyl]-6,7-dihydro-5H-2a-thia(2a-S(IV))-2,3,4a,7a-tetraazacyclopent[cd]indene-1,4(2H,3H)-dithione, prepared from 2,3-dialkyl substituted tetraazapentalene derivatives and p-xylylene diisothiocyanate, reacted with N,N'-dialkyl substituted diamines to give macrocyclic compounds by ring closure in good yields. These macrocyclic compounds were converted into desulfurized macrocyclic compounds by treatment with NaBH4 and CF3COOH.

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页码：865 / 868

页数：4

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