CATALYTIC STEREOSELECTIVE SYNTHESIS OF 2-AMINO-2-DEOXY-ALPHA-D-GLUCOPYRANOSIDES AND GALACTOPYRANOSIDES

被引：16

作者：

MATSUBARA, K

MUKAIYAMA, T

机构：

来源：

CHEMISTRY LETTERS | 1993年 / 12期

关键词：

D O I：

10.1246/cl.1993.2145

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the presence of a catalyst generated from SnCl4 and a silver salt, various 2-amino-2-deoxy-alpha-D-glucopyranosides or galactopyranosides are stereoselectively synthesized in good yields with high stereoselectivities through anomerization step starting from 1,3,4,6-tetra-0-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-beta-D-glucopyranose or galactopyranose and alkyl trimethylsilyl ethers, respectively.

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页码：2145 / 2148

页数：4

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