A NOVEL AND VERSATILE ACCESS TO FLUORINATED CARBOCYCLIC AND HETEROCYCLIC-COMPOUNDS EMPLOYING ELECTRON-RICH FLUORODIENES AS CYCLOADDITION COMPONENTS

被引：53

作者：

SHI, GQ ^{[1
]}

SCHLOSSER, M ^{[1
]}

机构：

[1] UNIV LAUSANNE,INST CHIM ORGAN,RUE BARRE 2,CH-1005 LAUSANNE,SWITZERLAND

来源：

TETRAHEDRON | 1993年 / 49卷 / 07期

关键词：

D O I：

10.1016/S0040-4020(01)90196-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The readily accessible 2-fluoro-1-trimethylsilyloxy-1,3-dienes undergo Diels-Alder type cycloaddition with a variety of dienophiles under mild conditions. In this way, fluoro-2-cyclohexenols, fluoro-2,5-dihydropyranols, fluoro-2,5-dihydro-2-pyridinols, fluoropyridines, fluoro-3,6-dihydro-1,2-oxazines and fluoropyrroles can be efficiently prepared.

引用

页码：1445 / 1456

页数：12

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