METALLIZATION OF POLYTHIOPHENES .1. INTERACTION OF VAPOR-DEPOSITED CU, AG AND AU WITH POLY(3-HEXYLTHIOPHENE) (P3HT)

被引：79

作者：

LACHKAR, A

SELMANI, A

SACHER, E

LECLERC, M

MOKHLISS, R

机构：

[1] FAC SCI SEMLALIA,DEPT CHIM,MARRAKECH,MOROCCO

[2] ECOLE POLYTECH,DEPT ENGN PHYS,MONTREAL H3C 3A7,QUEBEC,CANADA

[3] UNIV MONTREAL,DEPT CHIM,MONTREAL H3C 3J7,QUEBEC,CANADA

来源：

SYNTHETIC METALS | 1994年 / 66卷 / 03期

基金：

加拿大自然科学与工程研究理事会;

关键词：

METALLIZATION; POLYTHIOPHENES; POLY(3-HEXYLTHIOPHENE); DEPOSITION;

D O I：

10.1016/0379-6779(94)90069-8

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

We have studied the chemical structure and the nature of the reaction at the interfaces between a semiconducting conjugated polymer, poly(3-hexylthiophene) (P3HT), and the three coinage metals: Cu, Ag and Au. The initial stages of interface formation were followed, with the type and extent of chemical reaction being determined by XPS. It is found that both Cu and Ag react exclusively at the S atom of the P3HT while Au does not appear to react at all.

引用

收藏

页码：209 / 215

页数：7

相关论文

共 28 条

[1] VISIBLE-LIGHT EMISSION FROM SEMICONDUCTING POLYMER DIODES [J].

BRAUN, D ;

HEEGER, AJ .

APPLIED PHYSICS LETTERS, 1991, 58 (18) :1982-1984

[2] CHEMICAL TUNING OF ELECTROLUMINESCENT COPOLYMERS TO IMPROVE EMISSION EFFICIENCIES AND ALLOW PATTERNING [J].

BURN, PL ;

HOLMES, AB ;

KRAFT, A ;

BRADLEY, DDC ;

BROWN, AR ;

FRIEND, RH ;

GYMER, RW .

NATURE, 1992, 356 (6364) :47-49

[3] LIGHT-EMITTING-DIODES BASED ON CONJUGATED POLYMERS [J].

BURROUGHES, JH ;

BRADLEY, DDC ;

BROWN, AR ;

MARKS, RN ;

MACKAY, K ;

FRIEND, RH ;

BURN, PL ;

HOLMES, AB .

NATURE, 1990, 347 (6293) :539-541

[4] NEW SEMICONDUCTOR-DEVICE PHYSICS IN POLYMER DIODES AND TRANSISTORS [J].

BURROUGHES, JH ;

JONES, CA ;

FRIEND, RH .

NATURE, 1988, 335 (6186) :137-141

[5] POLY(3,3'-DIBUTOXY-2,2'-BITHIOPHENE) - A NEW HIGHLY CONJUGATED POLYTHIOPHENE DERIVATIVE [J].

CLOUTIER, R ;

LECLERC, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (17) :1194-1195

[6]

COTTON FA, 1980, ADV INORGANIC CHEM

[7] THE CHEMICAL AND ELECTRONIC-STRUCTURE OF THE INTERFACE BETWEEN ALUMINUM AND POLYTHIOPHENE SEMICONDUCTORS [J].

DANNETUN, P ;

BOMAN, M ;

STAFSTROM, S ;

SALANECK, WR ;

LAZZARONI, R ;

FREDRIKSSON, C ;

BREDAS, JL ;

ZAMBONI, R ;

TALIANI, C .

JOURNAL OF CHEMICAL PHYSICS, 1993, 99 (01) :664-672

[8]

FURUYAMA M, 1987, J ELECTRON SPECTROSC, V13, P59

[9] AN ALL-ORGANIC SOFT THIN-FILM TRANSISTOR WITH VERY HIGH CARRIER MOBILITY [J].

GARNIER, F ;

HOROWITZ, G ;

PENG, XH ;

FICHOU, D .

ADVANCED MATERIALS, 1990, 2 (12) :592-594

[10] THE APPLICATION OF PHOTOEMISSION, MOLECULAR-ORBITAL CALCULATIONS, AND MOLECULAR MECHANICS TO THE SILVER-POLY(PARA-PHENYLENE SULFIDE) INTERFACE [J].

GERENSER, LJ ;

GOPPERTBERARDUCCI, KE ;

BAETZOLD, RC ;

POCHAN, JM .

JOURNAL OF CHEMICAL PHYSICS, 1991, 95 (06) :4641-4649