A CONVENIENT METHOD FOR THE CONVERSION OF HALIDES TO ALCOHOLS

被引：24

作者：

ALEXANDER, J

RENYER, ML

VEERAPANANE, H

机构：

[1] INTERx Research Division of Merck and Co., Inc., Lawrence

来源：

SYNTHETIC COMMUNICATIONS | 1995年 / 25卷 / 23期

关键词：

D O I：

10.1080/00397919508011463

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The displacement of halides in unactivated primary bromides and iodides, allylic and benzylic primary and secondary bromides, and primary and secondary alpha-bromoketones by formats, using triethylammonium formate as the formylating agent, followed by acid or base catalyzed hydrolysis has been found to be an efficient method for the conversion of halides to alcohols.

引用

页码：3875 / 3881

页数：7

共 11 条

[1] ON THE PREPARATION OF 4-HYDROXYMETHYL-5-METHYL-1,3-DIOXOL-2-ONE [J].