HIGHLY ENANTIOSELECTIVE ADDITION OF (S)-LITHIOMETHYL 1-NAPHTHYL SULFOXIDE TO KETONES

被引：39

作者：

SAKURABA, H

USHIKI, S

机构：

[1] Department of Industrial Chemistry, Faculty of Engineering, Kanto Gakuin University, Yokohama, Kanagawa, 236, 4834, Kanazawa-Mutsuura

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 37期

关键词：

D O I：

10.1016/S0040-4039(00)98069-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The anion of (S)-(-)-methyl 1-naphthyl sulfoxide reacts enantioselectively with alkyl phenyl ketones to give (SsScJ-β-hydroxysulfoxides with diastereomeric excess (de) up to 100%. Optically pure (S)-tertiary alcohols are prepared by desulfurization of the corresponding diastereomers. © 1990.

引用

页码：5349 / 5352

页数：4

共 15 条

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